Emily Bett Rickards as Danielle Finley

Sebastian Stan as Bucky Barnes/The Winter Soldier

Sarah Michelle Gellar as Vanessa

Olivia Wilde as Jessabelle

with

Cobie Smulders as Maria Hill

Emily VanCamp as Agent 13

Jeremy Renner as Clint Barton/Hawkeye

Scarlett Johansson as Natasha Romanoff/Black Widow

and special appearances by 

Chris Evans as Steve Rogers/Captain America

Robert Redford as Alexander Pierce

Samuel L. Jackson as Nick Fury